Pure Good heroes who are vigilantes (that is, take the law into their own hands). While it is uncommon for Pure Goods to also be vigilantes given the actions of such will inevitably interfere with standard law and as a result, could wrongfully convict an innocent person or hurt innocent lives, in some cases it is also possible for a Pure Good to also be a vigilante if they don't cause harm to innocents in their quest for justice, don't opt for any violent methods (i.e. murder or torture) and lack any corrupting qualities.
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- Makoto Niijima
- Mara (She-Ra and the Princesses of Power)
- Mario (SMBZ)
- Mario (The Super Mario Bros. Movie)
- Mary "MK" Katherine
- Mega Man (Classic)
- Miles "Tails" Prower (Sonic the Hedgehog)
- Miles Morales (Insomniac's Marvel's Spider-Man)
- Miles Morales (Spider-Verse Films)
- Mon-El (Arrowverse)
- Mr. Knight
- Mugman
- Mugman (Last Drop of Greed)
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- Samurai Jack
- Sash Lilac
- Shantae
- Shifu
- Silver the Hedgehog
- Slippy Toad
- Sophia (Persona 5 Strikers)
- Spider-Man (Amazing Spider-Man)
- Spider-Man (Insomniac's Marvel's Spider-Man)
- Spider-Man (Marvel Cinematic Universe)
- Spider-Man (Marvel)
- Spider-Man (Raimiverse)
- Spider-Man (Spider-Man: Fake Red)
- Spider-Man (Spider-Man: The Animated Series)
- Spider-Man (The Spectacular Spider-Man)
- Spider-Man (What If...?)
- SpongeBob SquarePants (Mr. Krabs' Unquenchable Blood Lust)
- Star-Lord (T'Challa)
- Superman (DC)
- Superman (My Adventures with Superman)